発表論文

総説・著書

• 新規キラル合成ブロックの創製を基盤とする生物活性テルペノイドの合成研究．
  山越博幸，中村精一　 “月刊ファインケミカル2020年3月号 天然物合成化学の最新動向”
  シーエムシー出版，2020，pp 5–11．
  
  
• Stereocontrolled Construction of 1,2-cis-α-Glycosidic Linkages Using Glycosyl Diphenyl Phosphates and Synthesis of α-Galactosylceramide KRN7000.
  Nambu, H.; Nakamura, S.; Suzuki, N.; Hashimoto, S. Trends Glycosci. Glycotechnol. 2010, 22, 26–40. [DOI]
  
  
• ピンナトキシンＡの全合成．
  中村精一，橋本俊一　 “天然物全合成の最新動向”
  北　泰行監修，シーエムシー出版，2009，pp 244–259．
  
  
• カルシウムチャネル活性化物質ピンナトキシンＡの全合成．
  中村精一，橋本俊一　ファルマシア　2009，45，427–432．
  
  
• Phosphates, Phosphites and Other O–P Derivatives.
  Nakamura, S.; Nambu, H.; Hashimoto, S. In Handbook of Chemical Glycosylation: Advances in Stereoselectivity and Therapeutic Relevance; Demchenko, A. V., Ed.; Wiley-VCH: Weinheim, 2008; pp 223–259.
  
  
• ザラゴジン酸の全合成：ロジウム(II)触媒を用いる骨格形成反応．
  中村精一，穴田仁洋，橋本俊一　“現代化学増刊43 最新有機合成化学 —ヘテロ原子･遷移金属化合物を用いる合成—”
  奈良坂紘一，岩澤伸治編，東京化学同人，2005，pp 151–165．
  
  
• Total Synthesis of the Squalene Synthase Inhibitor Zaragozic Acid C.
  Nakamura, S. Chem. Pharm. Bull. 2005, 53, 1–10. [DOI]

最近の主要な発表論文

• Oxidative Generation of Isobenzofurans from Phthalans: Application to the Formal Synthesis of (±)-Morphine.
  Kage, M.; Yamakoshi, H.; Tabata, M.; Ohashi, E.; Noguchi, K.; Watanabe, T.; Uchida, M.; Takada, M.; Ikeuchi, K.; Nakamura, S. Chem. Sci. 2024, 15, 19070–19076. [DOI]
  ※有機合成化学に関する最新の論文から特に優れた研究を専門家が選び紹介している専門誌Synfactsで紹介して頂きました。
  
  
• Stereoselective Synthesis of the DE Ring Portion of Kadcoccilactone A by a Radical Addition/Cyclization Approach.
  Noguchi, K.; Saito, S.; Yamakoshi, H.; Nakamura, S. Eur. J. Org. Chem. 2022, e202201201. [DOI]
  
  
• Stereoselective 1,4-Addition of Primary Alcohols to γ-Alkoxy-α,β-unsaturated Esters.
  Inatomi, S.; Takayanagi, Y.; Watanabe, K.; Toita, A.; Yamakoshi, H.; Nakamura, S. Synthesis 2021, 53, 161–174. [DOI]
  
  
• Total Syntheses of Marrubiin and Related Labdane Diterpene Lactones.
  Sakagami, Y.; Kondo, N.; Sawayama, Y.; Yamakoshi, H.; Nakamura, S. Molecules 2020, 25, 1610. [DOI]
  
  
• Second-Generation Synthesis of a Chiral Building Block for Oxygenated Terpenoids via a Ring-Contractive Coupling with a Secondary Alcohol.
  Saito, S.; Yamakoshi, H.; Nakamura, S. Heterocycles 2019, 99, 1086–1094. （福山 透教授記念号）[DOI]
  
  
• Tandem Oxidation/Cyclization Reaction of 4-(Arylmethyl)oxy-2-diazobutyrate Derivatives.
  Kondo, H.; Nagano, S.; Yamakoshi, H.; Nakamura, S. Heterocycles 2018, 97, 894–915. （富岡 清教授記念号）[DOI]
  
  
• Cyclization of α-Diazo Esters Triggered by Oxidation: A Facile Preparation of 5-Aryl-2,3-dihydrofuran-4-carboxylates.
  Kondo, H.; Yamakoshi, H.; Kimura, A.; Nakamura, S. ChemistrySelect 2017, 2, 5646–5649. [DOI]
  
  
• A Double Hemiketal Formation/Hetero-Michael Addition Approach to the [6,5,5]-Dispiroketal System of Spirolides.
  Yamakoshi, H.; Toita, A.; Igari, T.; Takeda, K.; Hashimoto, S.; Nakamura, S. Heterocycles 2017, 95, 934–949. （柴�武ｳ勝教授記念号）[DOI]
  
  
• Total Syntheses of (+)-Marrubiin and (–)-Marrulibacetal.
  Yamakoshi, H.; Sawayama, Y.; Akahori, Y.; Kato, M.; Nakamura, S. Org. Lett. 2016, 18, 3430–3433. [DOI]
  
  
• Construction of Bridged Polycyclic Systems by Polyene Cyclization.
  Suzuki, K.; Yamakoshi, H.; Nakamura, S. Chem. Eur. J. 2015, 21, 17605–17609. [DOI]
  
  
• Synthesis of the Tetrasaccharide Repeating Unit from Acinetobacter baumannii Serogroup O18 Capitalizing on Phosphorus-Containing Leaving Groups.
  Arihara, R.; Kakita, K.; Yamada, K.; Nakamura, S.; Hashimoto, S. J. Org. Chem. 2015, 80, 4278–4288. [DOI]
  
  
• Glycosylation with 2-Acetamido-2-deoxyglycosyl Donors at a Low Temperature: Scope of the Non-Oxazoline Method.
  Arihara, R.; Kakita, K.; Suzuki, N.; Nakamura, S.; Hashimoto, S. J. Org. Chem. 2015, 80, 4259–4277. [DOI]
  
  
• Stereoselective Synthesis of the CDE Ring System of Antitumor Saponin Scillascilloside E-1.
  Akahori, Y.; Yamakoshi, H.; Hashimoto, S.; Nakamura, S. Org. Lett. 2014, 16, 2054–2057. [DOI]
  
  
• Synthesis of Chiral Building Blocks for Oxygenated Terpenoids through a Simultaneous and Stereocontrolled Construction of Contiguous Quaternary Stereocenters by an Ireland–Claisen Rearrangement.
  Akahori, Y.; Yamakoshi, H.; Sawayama, Y.; Hashimoto, S.; Nakamura, S. J. Org. Chem. 2014, 79, 720–735. [DOI]
  
  
• Total Syntheses of (+)-Polygalolide A and (+)-Polygalolide B: Elucidation of the Absolute Stereochemistry and Biogenetic Implications.
  Sugano, Y.; Kikuchi, F.; Toita, A.; Nakamura, S.; Hashimoto, S. Chem. Eur. J. 2012, 18, 9682–9690. [DOI]
  
  
• A Stereocontrolled Construction of 2-Azido-2-deoxy-1,2-cis-α-galactosidic Linkages Utilizing 2-Azido-4,6-O-benzylidene-2-deoxygalactopyranosyl Diphenyl Phosphates: Stereoselective Synthesis of Mucin Core 5 and Core 7 Structures.
  Kakita, K.; Tsuda, T.; Suzuki, N.; Nakamura, S.; Nambu, H.; Hashimoto, S. Tetrahedron 2012, 68, 5005–5017. [DOI]
  
  
• Total Synthesis of (+)-Condylocarpine, (+)-Isocondylocarpine, and (+)-Tubotaiwine.
  Martin, C. L.; Nakamura, S.; Otte, R.; Overman, L. E. Org. Lett. 2011, 13, 138–141. [DOI]
  
  
• Direct and Stereoselective Synthesis of 2-Azido-2-deoxy-β-D-Mannosides Using the Phosphate Method.
  Nakamura, S.; Tsuda, T.; Suzuki, N.; Hashimoto, S. Heterocycles 2009, 77, 843–848. [DOI]
  
  
• Total Synthesis of Pinnatoxin A.
  Nakamura, S.; Kikuchi, F.; Hashimoto, S. Angew. Chem., Int. Ed. 2008, 47, 7091–7094. [DOI]
  
  
• Catalytic Stereoselective Glycosidation with Glycosyl Diphenyl Phosphates: Rapid Construction of 1,2-cis-α-Glycosidic Linkages.
  Koshiba, M.; Suzuki, N.; Arihara, R.; Tsuda, T.; Nambu, H.; Nakamura, S.; Hashimoto, S. Chem. Asian J. 2008, 3, 1664–1677. [DOI]
  
  
• Stereoselective Synthesis of a C1–C6 Fragment of Pinnatoxin A via a 1,4-Addition/Alkylation Sequence.
  Nakamura, S.; Kikuchi, F.; Hashimoto, S. Tetrahedron: Asymmetry 2008, 19, 1059–1067. [DOI]
  
  
• A Short, Formal, Biomimetic Synthesis of (±)-Polygalolides A and B.
  Snider, B. B.; Wu, X.; Nakamura, S.; Hashimoto, S. Org. Lett. 2007, 9, 873–874. [DOI]
  
  
• Total Syntheses of Zaragozic Acids A and C by a Carbonyl Ylide Cycloaddition Strategy.
  Hirata, Y.; Nakamura, S.; Watanabe, N.; Kataoka, O.; Kurosaki, T.; Anada, M.; Kitagaki, S.; Shiro, M.; Hashimoto, S. Chem. Eur. J. 2006, 12, 8898–8925. [DOI]
  
  
• Total Synthesis and Absolute Stereochemistry of Polygalolides A and B.
  Nakamura, S.; Sugano, Y.; Kikuchi, F.; Hashimoto, S. Angew. Chem., Int. Ed. 2006, 45, 6532–6535. [DOI]
  
  
• Total Synthesis of Zaragozic Acid C by an Aldol-Based Strategy.
  Nakamura, S.; Sato, H.; Hirata, Y.; Watanabe, N.; Hashimoto, S. Tetrahedron 2005, 61, 11078–11106. [DOI]
  
  
• Direct and Stereoselective Synthesis of β-D-Mannosides Using 4,6-O-Benzylidene-Protected Mannosyl Diethyl Phosphite as a Donor.
  Tsuda, T.; Arihara, R.; Sato, S.; Koshiba, M.; Nakamura, S.; Hashimoto, S. Tetrahedron 2005, 61, 10719–10733. [DOI]
  
  
• Direct and Stereoselective Synthesis of 2-Acetamido-2-deoxy-β-D-glycopyranosides by Using the Phosphite Method.
  Arihara, R.; Nakamura, S.; Hashimoto, S. Angew. Chem., Int. Ed. 2005, 44, 2245–2249. [DOI]
  
  
• A Highly Stereoselective Construction of 1,2-trans-β-Glycosidic Linkages Capitalizing on 2-Azido-2-deoxy-D-glycosyl Diphenyl Phosphates as Glycosyl Donors.
  Tsuda, T.; Nakamura, S.; Hashimoto, S. Tetrahedron 2004, 60, 10711–10737. [DOI]
  
  
• Total Synthesis of the Squalene Synthase Inhibitor Zaragozic Acid C by a Carbonyl Ylide Cycloaddition Strategy.
  Nakamura, S.; Hirata, Y.; Kurosaki, T.; Anada, M.; Kataoka, O.; Kitagaki, S.; Hashimoto, S. Angew. Chem., Int. Ed. 2003, 42, 5351–5355. [DOI]
  
  
• A Stereocontrolled Construction of 2-Azido-2-deoxy-1,2-trans-β-glycosidic Linkages Utilizing 2-Azido-2-deoxyglycopyranosyl Diphenyl Phosphates.
  Tsuda, T.; Nakamura, S.; Hashimoto, S. Tetrahedron Lett. 2003, 44, 6453–6457. [DOI]
  
  
• Direct and Stereoselective Construction of β-Mannosidic Linkages Capitalizing on 4,6-O-Benzylidene-Protected D-Mannopyranosyl Diethyl Phosphite.
  Tsuda, T.; Sato, S.; Nakamura, S.; Hashimoto, S. Heterocycles 2003, 59, 509–515. [DOI]
  
  
• A Highly Stereoselective Synthesis of the C10–C31 (BCDEF Ring) Portion of Pinnatoxin A.
  Nakamura, S.; Inagaki, J.; Sugimoto, T.; Ura, Y.; Hashimoto, S. Tetrahedron 2002, 58, 10375–10386. [DOI]
  
  
• Studies Directed toward the Total Synthesis of Pinnatoxin A: Synthesis of the 6,5,6-Dispiroketal (BCD Ring) System by Double Hemiketal Formation/Hetero-Michael Addition Strategy.
  Nakamura, S.; Inagaki, J.; Kudo, M.; Sugimoto, T.; Obara, K.; Nakajima, M.; Hashimoto, S. Tetrahedron 2002, 58, 10353–10374. [DOI]
  
  
• A Stereoselective Synthesis of the C10–C31 (BCDEF Ring) Portion of Pinnatoxin A.
  Nakamura, S.; Inagaki, J.; Sugimoto, T.; Kudo, M.; Nakajima, M.; Hashimoto, S. Org. Lett. 2001, 3, 4075–4078. [DOI]

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